All About Belgium

Discusses its institutions, land and people, history and politics, the economy, art and culture, tourism, sports, education and science.
http://www.belgium.be/eportal/application?origin=navigationBanner.jsp&event=bea.portal.framework.internal.refresh&pageid=indexPage&navId=2420

CIA World Factbook: Belgium

Features a map and brief descriptions of geography, economy, government, and people.
http://www.cia.gov/cia/publications/factbook/geos/be.html